Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10phen)(OH)x]3[Cr(OH)6Mo6O18]•16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)

Özbek Avci, HÜLYA

doi:10.18596/jotcsa.1215066

Synthesis and Characterization of New Anderson-Type Polyoxometalates: [M((1,10phen)(OH)x]3[Cr(OH)6Mo6O18]•16H2O (M=Cr, Mn, Co, Ni, Cu; x=1,2)

Atıf İçin Kopyala

Özbek Avci H.

Journal of the Turkish Chemical Society, Section A: Chemistry, cilt.10, sa.2, ss.315-324, 2023 (Scopus)

Yayın Türü: Makale / Tam Makale
Cilt numarası: 10 Sayı: 2
Basım Tarihi: 2023
Doi Numarası: 10.18596/jotcsa.1215066
Dergi Adı: Journal of the Turkish Chemical Society, Section A: Chemistry
Derginin Tarandığı İndeksler: Scopus, TR DİZİN (ULAKBİM)
Sayfa Sayıları: ss.315-324
Anahtar Kelimeler: Anderson-Evans, Chromium, Molybdenum, Polyoxometalate
Manisa Celal Bayar Üniversitesi Adresli: Evet

Özet

Five new Anderson-type polyoxometalate compounds [M((1,10-phen) (OH)x]3[Cr(OH)6Mo6O18]∙16H2O (M=Cr(1), Mn(2), Co(3),Ni(4),Cu(5);x=1,2) were obtained from Na2MoO42H2O and CrCl3∙6H2O within acidic aqueous medium (pH=2-3). The compounds are characterized by means of FT-IR, TGA, ICP-MS, and elemental analysis techniques. The structural analysis show that compounds (1-5) consist of a Anderson-type polyanion [Cr(OH)6Mo6O18]3-.