Co-ordination of copper and silver by [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6]

---

Demirhan F., Irişli S., N. Salek S., Şentürk O. S., Went M. J., Jeffery J. C.

Journal of Organometallic Chemistry, cilt.453, sa.2, 1993 (Scopus)

• Yayın Türü: Makale / Tam Makale
• Cilt numarası: 453 Sayı: 2
• Basım Tarihi: 1993
• Doi Numarası: 10.1016/0022-328x(93)83134-h
• Dergi Adı: Journal of Organometallic Chemistry
• Derginin Tarandığı İndeksler: Scopus
• Manisa Celal Bayar Üniversitesi Adresli: Hayır

Özet

The thiamacrocycle [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6] reacts with Ag[BF4] and PPh3 to afford the fluxional compound [Co2{μ-C2(CH2SCH2)2S}(CO)6(AgPPh3)][BF4], the structure of which has been established by X-ray crystallography, and with [Cu(CH3-CN)4][PF6] to afford [Co2{μ-C2(CH2SCH2CH2)2S}(CO)6(CuCH3-CN)][PF6], which undergoes phosphine sustitution. © 1993.