Environmental and Non-Toxic New Radiation Shielding Materials Alternative to Lead: Preparation, Evaluation of Their Effectiveness on Gamma Attenuation Coefficients, and Investigation of Thermal Properties


KÖRPINAR B., AKAT H.

Polymers for Advanced Technologies, cilt.37, sa.2, 2026 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 37 Sayı: 2
  • Basım Tarihi: 2026
  • Doi Numarası: 10.1002/pat.70510
  • Dergi Adı: Polymers for Advanced Technologies
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus, Chemical Abstracts Core, Chimica, Compendex, INSPEC
  • Anahtar Kelimeler: linear attenuation coefficients(μ), metal oxide, oxidized polyethylene, thermal decomposition
  • Manisa Celal Bayar Üniversitesi Adresli: Evet

Özet

In this study, composite materials were prepared using oxidized polyethylene wax and low-density oxidized polyethylene with metal oxides—tungsten, bismuth, zinc, lead, and titanium—at varying concentrations (10%–50%). Characterization was performed using Fourier-transformed infrared spectroscopy, x-ray diffraction, scanning electron microscopy, thermogravimetric/differential thermogravimetric analysis, and particle distribution analysis. Gamma ray linear attenuation coefficients (μ) were measured using a NaI(Tl) scintillation detector, while theoretical values were calculated via the XCOM platform. SEM results confirmed homogeneous dispersion of metal oxides in the polymer matrix without agglomeration. Radiation shielding parameters, such as half-value layer, tenth-value layer, and mean free path, were also calculated. The inclusion of high-density, high atomic number oxides (e.g., Bi2O3: 8.90 g/cm3, Z = 83) aimed to enhance gamma ray interaction. Thermal analysis showed that increasing metal oxide content improved the composites' thermal stability. Among all samples, the 50% Bi2O3-low-density oxidized polyethylene composite exhibited the highest gamma ray absorption and the lowest required shielding thickness, making it the most effective material.