Absorption and photoluminescence spectroscopy of Er 3+-doped SrAl 2O 4 ceramic phosphors


Ayvackl M., Khatab A., EGE A., ŞABİKOĞLU İ., Henini M., Can N.

Philosophical Magazine Letters, cilt.92, sa.4, ss.194-201, 2012 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 92 Sayı: 4
  • Basım Tarihi: 2012
  • Doi Numarası: 10.1080/09500839.2011.652685
  • Dergi Adı: Philosophical Magazine Letters
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.194-201
  • Anahtar Kelimeler: photoluminescence, solid-state reaction method, phosphors, SrAl2O4, rare earths, optical spectroscopy, optical properties
  • Manisa Celal Bayar Üniversitesi Adresli: Evet

Özet

A spectroscopic characterization of Er 3+-doped SrAl 2O 4 phosphor materials synthesized by a solid-state reaction method with Er concentrations varying from 0.1 to 1 mol% has been performed by studying photoluminescence (PL) in the temperature range 10 to 360K and absorption spectra. PL signals containing five emission bands at 1492, 1529, 1541, 1558, and 1600nm, respectively, have been observed at room temperature for Er 3+ transitions in the near infrared region. The samples exhibit a main luminescence peak at 1.54 μm, which is assigned to recombination via an intra-4f Er 3+ transition. Sharp bands centered at around 378, 488, 521, 651, 980, 1492, and 1538nm in the absorption spectra can be associated with transitions from 4I 15/2 level to 2H 9/2, 4F 7/2, 2H 11/2, 4F 9/2, 4I 11/2, 2H 11/2, and 4I 13/2 levels, respectively. The sharp emission peaks and excellent luminescence properties show that SrAl 2O 4 is a suitable host for rare-earth-doped phosphors, which may be suitable for optical applications. © 2012 Taylor & Francis.