Metal complexes of guanidine-substituted alkyl ligands: An unsolvated monomeric two-coordinate organolithium

Coles M. P., Sözerli S. E., Smith J. D., Hitchcock P. B.

Organometallics, cilt.26, sa.27, ss.6691-6693, 2007 (SCI-Expanded, Scopus) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 26 Sayı: 27
  • Basım Tarihi: 2007
  • Doi Numarası: 10.1021/om700963c
  • Dergi Adı: Organometallics
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.6691-6693
  • Manisa Celal Bayar Üniversitesi Adresli: Hayır

Özet

Single-crystal X-ray diffraction of MC(SiMe3) 2(SiMe2hpp) (M = Li, K; hppH = 1,3,4,6,7,8,-hexahydro-2H- pyrimido[1,2-a]pyrimidine) showed nonsolvated organometallic compounds in which the iminonitrogen of the guanidine forms strong intramolecular bonds to generate six-membered metallacycles. © 2007 American Chemical Society.