Thermal and mechanical properties of LDPE by the effects of organic peroxides

ŞİRİN K., Cengel Ö., Canli M.

Polymers for Advanced Technologies, vol.28, no.7, pp.876-885, 2017 (SCI-Expanded, Scopus) identifier

  • Publication Type: Article / Article
  • Volume: 28 Issue: 7
  • Publication Date: 2017
  • Doi Number: 10.1002/pat.3992
  • Journal Name: Polymers for Advanced Technologies
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.876-885
  • Keywords: cross-linking, low-density polyethylene, mechanical properties, organic peroxide, thermal properties
  • Manisa Celal Bayar University Affiliated: Yes

Abstract

In this study, the effect of different organic peroxides on different types of low-density polyethylene (LDPE) was investigated. LDPE products like F2-21T, F5-21T, and I22-19T were mixed in different proportions with dialkyl peroxide, dibenzoyl peroxide, and dilauroyl peroxide. Melt flow rates, mechanical properties (tensile strength at yield, tensile strength at break, elongation at break, and stress-strain effect), thermal analysis (differential scanning calorimetric and thermogravimetric analysis), and scanning electron microscopy images of the prepared mixtures were examined. Cross-linking occurred in the structure of LDPE types having different molecular weight distribution by the addition of even small amounts of peroxide (e.g. 0–0.12 wt%). Copyright © 2017 John Wiley & Sons, Ltd.