High oxidation state aqueous organometallics. Formation and structure of an oxo-centred Cp*Movtrinuclear cation by chemical reduction of Cp*2Mo2O5

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Demirhan F., Gun J., Lev O., Modestov A., Poli R., Richard P.

Journal of the Chemical Society, Dalton Transactions, sa.10, ss.2109-2111, 2002 (Scopus)

• Yayın Türü: Makale / Tam Makale
• Basım Tarihi: 2002
• Doi Numarası: 10.1039/b203583a
• Dergi Adı: Journal of the Chemical Society, Dalton Transactions
• Derginin Tarandığı İndeksler: Scopus
• Sayfa Sayıları: ss.2109-2111
• Manisa Celal Bayar Üniversitesi Adresli: Evet

Özet

Reduction of Cp*2Mo2O5by zinc/CF3CO2H in MeOH-H2O yields a salt which is composed of [Cp*3Mo3O4(O2CCF 3)3]+and [Zn2(O2CCF3)6]2ions after crystallisation from THF-Et2O.