Removal of heavy metals in wastewater by using zeolite nano-particles impregnated polysulfone membranes


YÜREKLİ Y.

Journal of Hazardous Materials, cilt.309, ss.53-64, 2016 (SCI-Expanded) identifier identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 309
  • Basım Tarihi: 2016
  • Doi Numarası: 10.1016/j.jhazmat.2016.01.064
  • Dergi Adı: Journal of Hazardous Materials
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.53-64
  • Anahtar Kelimeler: Adsorption, Hybrid membrane, Metal removal, Ultrafiltration, Zeolite nanoparticles
  • Manisa Celal Bayar Üniversitesi Adresli: Evet

Özet

In this study, the adsorption and the filtration processes were coupled by a zeolite nanoparticle impregnated polysulfone (PSf) membrane which was used to remove the lead and the nickel cations from synthetically prepared solutions. The results obtained from X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) analysis indicated that the synthesized zeolite nanoparticles, using conventional hydrothermal method, produced a pure NaX with ultrafine and uniform particles. The performance of the hybrid membrane was determined under dynamic conditions. The results also revealed that the sorption capacity as well as the water hydraulic permeability of the membranes could both be improved by simply tuning the membrane fabricating conditions such as evaporation period of the casting film and NaX loading. The maximum sorption capacity of the hybrid membrane for the lead and nickel ions was measured as 682 and 122 mg/g respectively at the end of 60 min of filtration, under 1 bar of transmembrane pressure. The coupling process suggested that the membrane architecture could be efficiently used for treating metal solutions with low concentrations and transmembrane pressures.