Strong visible and near-infrared cathodoluminescence in alkali feldspar


KARABULUT Y., Canimoglu A.

Spectroscopy Letters, vol.47, no.6, pp.458-464, 2014 (SCI-Expanded, Scopus) identifier identifier

  • Publication Type: Article / Article
  • Volume: 47 Issue: 6
  • Publication Date: 2014
  • Doi Number: 10.1080/00387010.2013.808231
  • Journal Name: Spectroscopy Letters
  • Journal Indexes: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Page Numbers: pp.458-464
  • Keywords: Cathodoluminescence, Mn2+, Feldspars, Fe3+
  • Manisa Celal Bayar University Affiliated: Yes

Abstract

In this study, cathodoluminescence (CL) spectroscopy at direct current and alternating current under the sample temperature condition of 40-293 K using different modulation frequencies is presented for alkali feldspar from the Dartmoor granite (UK). These feldspars contain strain-controlled lamellar crypto-and microperthites that are cross-cut by strain-free deuteric microperthites. The CL spectra of the alkali feldspar at room and low temperature confirm that the observed emission peaked at ∼460 nm could be associated with Al-O--Al or Ti impurity centers, yellow emission ∼560 nm could be associated with the presence of the centers such as radiation-induced defect centers, and ∼756 nm emission could be associated with the Fe3+ impurity center on T1 and T2 sites. The consequence of their association is to produce different luminescence properties such as intensity, peak wavelength, and band shape. © 2014 Copyright Taylor & Francis Group, LLC.