Comparative studies on thermoluminescence characteristics of non-doped Mg2SiO4 prepared via a solid-state reaction technique and wet-chemical method: An unusual heating rate dependence


DOĞAN T., AKÇA ÖZALP S., YÜKSEL M., KÜÇÜK N., AYVACIKLI M., KARABULUT Y., ...Daha Fazla

Journal of Alloys and Compounds, cilt.795, ss.261-268, 2019 (SCI-Expanded) identifier

  • Yayın Türü: Makale / Tam Makale
  • Cilt numarası: 795
  • Basım Tarihi: 2019
  • Doi Numarası: 10.1016/j.jallcom.2019.04.331
  • Dergi Adı: Journal of Alloys and Compounds
  • Derginin Tarandığı İndeksler: Science Citation Index Expanded (SCI-EXPANDED), Scopus
  • Sayfa Sayıları: ss.261-268
  • Anahtar Kelimeler: Heating rate, Mg2SiO4, Thermoluminescence, XRD
  • Manisa Celal Bayar Üniversitesi Adresli: Evet

Özet

Magnesium orthosilicate (Mg2SiO4)was synthesized via a traditional solid-state reaction and a wet chemical route. This study primarily reported the thermoluminescence (TL)behavior of Mg2SiO4 host. X-ray diffraction pattern revealed that Mg2SiO4 exhibits orthorhombic structure matched with JCPDS card 900-6398. Dose response, reproducibility and trap parameters of TL glow curves were evaluated to clearly reveal TL features. Two TL glow peaks situated at 81 °C and 192 °C were monitored at a heating rate of 2 °Cs−1. We observed anomalous heating rate effect for the peak centered at 192 °C whilst TL intensity of the peak at 81 °C decreases with elevating heating rate. Trap depths of the electrons within the trap centers were found to be 1.04 ± 0.01eV and 1.37 ± 0.01eV for both methods using peak shape (PS)method. Distribution of trap centers was examined using the Tmax−Tstop method and this case indicated that the glow curves consist of single TL peaks. The intensity of TL glow curves exhibited a good linear dose response under total area up to 20 Gy. A comparison of the two preparation techniques revealed that TL characteristics of this phosphor are partly dependent and Mg2SiO4 could be a promising material for dosimetric application.